Relationship between Molecular Structure and Induced Spontaneous Polarization for Chiral Dopants Containing an Optically Active Lactone

T. Ikemoto Tokyo Research Laboratories, Mitsubishi Rayon Co., Ltd., Noborito, Tama-ku, Kawasaki, 214, Japan; Central Research Laboratories, Mitsubishi Rayon Co., Ltd., Miyuki-cho, Otake, 739-06, Japan

K. Sakashita Tokyo Research Laboratories, Mitsubishi Rayon Co., Ltd., Noborito, Tama-ku, Kawasaki, 214, Japan; Central Research Laboratories, Mitsubishi Rayon Co., Ltd., Miyuki-cho, Otake, 739-06, Japan

Y. Kageyama Tokyo Research Laboratories, Mitsubishi Rayon Co., Ltd., Noborito, Tama-ku, Kawasaki, 214, Japan; Central Research Laboratories, Mitsubishi Rayon Co., Ltd., Miyuki-cho, Otake, 739-06, Japan

F. Onuma Tokyo Research Laboratories, Mitsubishi Rayon Co., Ltd., Noborito, Tama-ku, Kawasaki, 214, Japan

Y. Shibuya Tokyo Research Laboratories, Mitsubishi Rayon Co., Ltd., Noborito, Tama-ku, Kawasaki, 214, Japan

K. Ichimura Tokyo Research Laboratories, Mitsubishi Rayon Co., Ltd., Noborito, Tama-ku, Kawasaki, 214, Japan

K. Mori Department of Agricultural Chemistry, the University of Tokyo, Yayoi, Bunkyo-ku, Tokyo, 113, Japan

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Abstract

A series of new optically active γ-lactones were synthesized. The relationship between molecular structures and induced spontaneous polarization of optically active γ-lactones and δ-lactones has been investigated. The molecular shapes of chiral dopants, especially the alkyl chains extending from a lactone ring, were found to play important roles in the generation of spontaneous polarization.

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Relationship between Molecular Structure and Induced Spontaneous Polarization for Chiral Dopants Containing an Optically Active Lactone

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Relationship between Molecular Structure and Induced Spontaneous Polarization for Chiral Dopants Containing an Optically Active Lactone

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