Hydrogen Bonding Networks in Bilayered Crystals Composed of Facially Amphiphilic Compounds

Mikiji Miyata Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido 1-1, Gifu, 501-11, Japan

Kazuki Sada Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido 1-1, Gifu, 501-11, Japan

Yoshitaka Yasuda Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido 1-1, Gifu, 501-11, Japan

Kunio Miki Research Laboratory of Resources Utilization, Tokyo Institute of Technology, Nagatsuta, Midori-ku, Yokohama, 227, Japan

Abstract

Highly asymmetric and facially amphiphilic compounds, cholic acid and its derivatives, form asymmetric bilayers with variable hydrogen bonding networks. The bilayers are stacked in various modes to produce dynamical inclusion crystals suitable for molecular recognition and reaction.

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Hydrogen Bonding Networks in Bilayered Crystals Composed of Facially Amphiphilic Compounds

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Hydrogen Bonding Networks in Bilayered Crystals Composed of Facially Amphiphilic Compounds

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