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Original Articles

Reentrant Uniaxial-Biaxial Transition in Poly-Ethylene-Glycol Doped Lyotropic Liquid Crystals

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Pages 623-629 | Published online: 23 Sep 2006
 

Abstract

Interferometric measurements of the effect of a polymer gradativelly added in a lyotropic liquid crystal is reported here. Studies of the phase diagram, birefringence and critical exponents as a function of the polymer concentration are presented. Measurements of the optical birefringence as a function of temperature are performed with the micellar system potassium laurate, 1-decanol, and water doped with variable quantities of the polymer poly-ethylene-glycol (PEG). The transitions from the calamitic nematic phase to a reentrant discotic-biaxial-discotic phase were observed when increasing the PEG molar concentration. Our results confirm the critical properties of the uniaxial-to-biaxial nematic transition. The critical exponent for the order parameter (β = 0.38) obtained for the sample without PEG is in god agreement with the value caculated for the XY model. Some results with higher PEG doping concentration indicate that β is higher than 0.38 leading to the mean-field value.

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