Isotope Effect Study of κ-(BEDT-TTF)₂Cu(NCS)₂: Labeling in the Anion

Aravinda M. Kini Chemistry and Materials Science Divisions, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL, 60439, USA

H. Hau Wang Chemistry and Materials Science Divisions, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL, 60439, USA

John A. Schlueter Chemistry and Materials Science Divisions, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL, 60439, USA

James D. Dudek Chemistry and Materials Science Divisions, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL, 60439, USA

Urs Geiser Chemistry and Materials Science Divisions, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL, 60439, USA

K. Douglas Carlson Chemistry and Materials Science Divisions, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL, 60439, USA

Jack M. Williams Chemistry and Materials Science Divisions, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL, 60439, USA

Margaret E. Kelly Chemistry and Materials Science Divisions, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL, 60439, USA

Elizabeth Stevenson Chemistry and Materials Science Divisions, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL, 60439, USA

Adam S. Komosa Chemistry and Materials Science Divisions, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL, 60439, USA

Scott A. Sirchio Chemistry and Materials Science Divisions, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL, 60439, USA

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Abstract

Isotopic labeling in the anion of the organic superconductor κ-(BEDT-TTF)₂Cu(NCS)₂, with ¹³C and ¹⁵N isotopes in the thiocyanate groups, has been carried out. This labeling does not lead to an isotope effect on the superconducting transition temperature (T _c).

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Isotope Effect Study of κ-(BEDT-TTF)₂Cu(NCS)₂: Labeling in the Anion

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Isotope Effect Study of κ-(BEDT-TTF)₂Cu(NCS)₂: Labeling in the Anion