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Journal of Macromolecular Science, Part A
Pure and Applied Chemistry
Volume 43, 2006 - Issue 11
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Original Articles

Study on Nanofibers of Polyaniline via Interfacial Polymerization

Wei Li State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, P. R. China
,
Qinghua Zhang State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, P. R. ChinaCorrespondence[email protected]
,
Dajun Chen State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, P. R. China
&
Lan Li Research Center of Analysis and Measurement, Donghua University, Shanghai, P. R. China
Pages 1815-1824 | Published online: 07 Feb 2007
 
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Uniform polyaniline nanofibers were prepared by interfacial polymerization. The nanofibers had a diameter of 80 nm and a length of about 1μm. The effect of centrifugal force on the morphology of the nanofibers is discussed. In situ UV‐Vis spectra indicated that the interfacial polymerization process was similar to the solution polymerization process. An “expanded‐partly doped” stage of interfacial polymerization was observed for the first time in the in situ UV‐Vis spectra.

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