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Journal of Macromolecular Science, Part A
Pure and Applied Chemistry
Volume 44, 2007 - Issue 4
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Original Articles

Synthesis and Striking Fluorescence Properties of Hyperbranched Poly(amido amine)

Liang Cao Key Laboratory of Molecular Engineering of Polymers (Ministry of Education) and Department of Macromolecular Science, Fudan University, Shanghai, China
,
Wuli Yang Key Laboratory of Molecular Engineering of Polymers (Ministry of Education) and Department of Macromolecular Science, Fudan University, Shanghai, ChinaCorrespondence[email protected]
,
Changchun Wang Key Laboratory of Molecular Engineering of Polymers (Ministry of Education) and Department of Macromolecular Science, Fudan University, Shanghai, China
&
Shoukuan Fu Key Laboratory of Molecular Engineering of Polymers (Ministry of Education) and Department of Macromolecular Science, Fudan University, Shanghai, China
Pages 417-424 | Received 01 Aug 2006, Accepted 01 Sep 2006, Published online: 06 Mar 2007
 
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Hyperbranched poly(amido amine) (h‐PAMAM) was synthesized from different feed ratios of diethylene triamine and methyl acrylate by the simple one‐pot and commercial synthesis method. Reaction procedures and products were intensively studied by FTIR, inherent viscosity and fluorescence techniques. The ill‐structured h‐PAMAM shared similar chemical and physical properties with well defined poly(amido amine) (PAMAM) dendrimers in generation 2 or 3. Its strong fluorescence properties were influenced by pH values, solvents, concentrations, terminal groups and other factors.

5 Acknowledgements

This work was supported by the National Science Foundation of China (Grant No. 50233030, 50403011) and the Shanghai Rising‐Star Program (05QMX1404).

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