Abstract
Chloromethylated cross-linked polystyrene (CMCPS) microsphere is hydroxylated, obtaining hydroxylated cross-linked polystyrene microsphere (CPS-OH). Methacrylic acid (MAA) is grafted on the surface of CPS-OH microspheres by cerium salt-hydroxyl group redox initiation system, obtaining graft-polymerization functional microsphere CPS-g-PMAA. The chemical structure and physicochemistry characters of CPS-g-PMAA are characterized with infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The adsorption performance of the grafted microspheres CPS-g-PMAA for shikimic acid was mainly investigated and the adsorption mechanism was explored. The experiment results show that for the graft-polymerization of MAA, the suitable concentration of MAA in solution is 3.2 mol/L, the optimal concentration of initiator cerium salt and catalyzer Sulfuric acid is 1.3 × 10−2 and 0.3 1 mol/L, respectively, the appropriate temperature is 55 °C, and reaction time is 6 h, the grafting degree of PMAA can reach 43.3 g/100 g. The kinetics demonstrating adsorption kinetic of SA by CPS-g-PMAA is fitted PFO model in the first 50 min and is then fitted with the PSO model. The CPS-g-PMAA microsphere adsorbs SA via hydrogen bond interaction, the adsorption capacity reaches 92 mg/g in ethanol. The adsorption amount decreases with the increase of temperature, Freundlich isothermal model is fitted the adsorption experimental data.
Acknowledgments
This work was supported by the National Science Foundation for Young Scientists of China (21805249); Shanxi Province Science and Technology Foundation (201801D121069) and Engineering for Chemical Engineer and Technology (20190013).