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Abstract
Fluorine-containing liquid crystal polymers have excellent hydrophobic stability, making them attractive for use in the field of stable hydrophobic coatings. To improve the hydrophobic stability of fluoropolymers, a novel fluoro acrylate monomer (FAM) containing a rigid cyclohexane structure was simply synthesized using isophorone diisocyanate (IPDI), hydroxyethyl methacrylate (HEMA), and perfluorohexylethanol (S104) as raw materials and its homopolymer (PFAM) was prepared by radical solution polymerization. The structure, liquid crystal behavior, thermal properties, hydrophobic properties, and surface properties of FAM or PFAM and a reference substance, dodecafluoroheptyl methacrylate (DFMA) and its homopolymer (PDFMA), were studied using various techniques including FT-IR, NMR, GPC, XRD, POM, DSC, TGA, XPS, AFM, and static/dynamic contact angle measurements. The results indicate that FAM and PFAM are thermally liquid crystalline. PFAM's thermal stability is higher than that of PDFMA. The presence of a rigid cyclohexane structure facilitates the dense distribution of fluorocarbon chain tails of the homopolymer and also prevents surface reconstruction when the homopolymer comes into contact with polar liquids, resulting in improved hydrophobicity and hydrophobic stability. Thus, this study provides a straightforward method for the synthesis of fluoro acrylates with surface stability, highlighting their potential application in hydrophobic coatings.
GRAPHICAL ABSTRACT
Disclosure statement
No potential conflict of interest was reported by the authors.