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Supramolecular Chemistry Volume 22, 2010 - Issue 10
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Original Articles

Supramolecular behaviour of bulky arylboranes in the crystalline state

Christian Förster Institut für Organische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Straße 29, D-09596, Freiberg/Sachsen, Germany
,
Wilhelm Seichter Institut für Organische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Straße 29, D-09596, Freiberg/Sachsen, Germany
,
Anke Schwarzer Institut für Organische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Straße 29, D-09596, Freiberg/Sachsen, Germany
&
Edwin Weber Institut für Organische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Straße 29, D-09596, Freiberg/Sachsen, GermanyCorrespondence[email protected]
Pages 571-581 | Received 31 Mar 2010, Accepted 20 May 2010, Published online: 27 Jul 2010
 
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Abstract

The aromatic monoboranes 1, 2 and bisboranes 3, 4 of which 4 is a newly synthesised compound have been studied with reference to their supramolecular behaviour in the crystalline state. While the monoboranes crystallise purely, the bisboranes form channel-type solvent inclusions with m-xylene (3a) and nitrobenzene (4a) in the crystals, showing their potential as clathrate hosts in the realm of optically and electronically interesting compounds.

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