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Supramolecular Chemistry Volume 30, 2018 - Issue 5-6: SI: Jerry Atwood 75th Birthday Special Issue
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Articles

Sorption of CO2 in a hydrogen-bonded diamondoid network of sulfonylcalix[4]areneFootnote§

Michael A. SinnwellPhysical and Computational Science Directorate, Pacific Northwest National Laboratory, Richland, WA, USAORCID Iconhttp://orcid.org/0000-0002-6733-8335
ORCID Icon,
Jerry L. AtwoodDepartment of Chemistry, University of Missouri-Columbia, Columbia, MO, USAORCID Iconhttp://orcid.org/0000-0002-3350-9618
ORCID Icon &
Praveen K. ThallapallyPhysical and Computational Science Directorate, Pacific Northwest National Laboratory, Richland, WA, USACorrespondence[email protected]
ORCID Iconhttp://orcid.org/0000-0001-7814-4467
ORCID Icon
Pages 540-544 | Received 04 Nov 2017, Accepted 27 Jan 2018, Published online: 08 Feb 2018
 
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Abstract

An organic material, p-tert-butyltetrasulfonylcalix[4]arene, self-assembles via hydrogen bonding to form a diamondoid supramolecular network. Possessing discrete, zero-dimensional (0D) microcavities, the thiacalixarene derivative adsorbs CO2 at high pressures.

Acknowledgments

We thank the Department of Energy, Basic Energy Sciences, Division of Materials Sciences and Engineering, under award No. KC020105-FWP12152 and PNNL, a multiprogram national laboratory operated for the U.S. Department of Energy by Battelle Memorial Institute under Contract DE-AC05-76RL01830, for support.

Notes

§ Dedicated to Prof. Jerry L. Atwood for 75th Birthday.

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