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Original Articles

Separation of Sulfur Compounds from a Diesel Fraction by Ligand Exchange Chromatography

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Pages 1577-1601 | Received 05 Nov 2006, Accepted 06 Dec 2006, Published online: 17 Apr 2007
 

Abstract

Ligand exchange chromatography is reported as an effective technique for the separation of sulfur compounds from hydrocarbon molecules in a petroleum fraction. Palladium (II) chloride anhydrous, ferric chloride 6‐hydrate, copper (II) sulfate 5‐hydrate, silver nitrate, and tin (II) chloride 2‐hydrate were studied for their effectiveness to separate sulfur compounds present in a Kuwaiti diesel fraction. Tin, silver, and palladium salts were found to be more effective than iron and copper salts for the separation of sulfur compounds from aromatic hydrocarbon molecules present in the fraction by these studies.

Acknowledgments

The authors thank the management of the Kuwait Institute for Scientific Research (KISR) for the permission to use the facilities of the Petroleum Research and Studies Center (PRSC) to conduct the experimental work mentioned in this report. The authors also thank the management of the Kuwait Foundation for Advancement of Science, Kuwait, for the financial support of the project.

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