Application of a Continuous Kinetic Model for the Hydrocracking of Vacuum Gas Oil

Abstract

Hydrocracking is one of the most versatile petroleum refining processes for production of valuable products including gasoline, gas oil, and jet fuel. In this paper, a five-parameter continuous lumping model was used for kinetic modeling of hydrocracking of vacuum gas oil (VGO). The model parameters were estimated from industrial data obtained from a fixed bed reactor operating at an average temperature of 400°C and residence time of 0.3 h. Product distributions were obtained in terms of the weight fraction of various boiling point cuts. The model parameters were estimated using the Nelder-Mead optimization procedure and were correlated with temperature. Comparison of experimental and predicted product distributions indicated that the model was successful in predicting the products from hydrocracking reactions.

Keywords:

• continuous lumping
• hydrocracking
• Isomax
• kinetics
• vacuum gas oil