Removal of Cr from tannery sludge by indigenous sulfur-oxidizing bacteria

Abstract

The aim of the present study was to examine Cr removal from tannery sludge by bioleaching method using indigenous sulfur-oxidizing bacteria with special emphasis on the influence of bioleaching process on sludge settleability. Chemical leaching with sulfuric acid was designed as the control. The results showed that the inoculation of sulfur-oxidizing bacteria and the addition of elemental sulfur were effective in removing Cr from tannery sludge. After 144 hours of bioleaching, 98% of Cr could be leached. Although it took only 8 hours to reduce the sludge pH from 7.8 to about 2.0 by chemical leaching as compared to 144 hours for bioleaching treatment, chemical leaching removed only 91% of the total Cr. Regardless of bioleaching and chemical leaching treatments, sludge settleability improved considerably with a decrease in sludge pH. Bioleaching treatment performed better than chemical leaching in terms of the percentage of settled sludge and the effluent suspended solids (ESS) content in sludge supernatant. Nevertheless, further work should be carried out to investigate the precise mechanisms leading to such enhanced sludge settleability during sludge bioleaching process.

Keywords:

• Bioleaching
• chromium
• tannery sludge
• sulfur
• sludge settleability

Acknowledgments

The work described in this paper was supported partly by a grant from the National Natural Science Foundation of China (NSFC/20707024), and partly by a research grant from the Ocean University of China (OUC). The authors would like to thank the company of Qingdao Head Tannery (China) for providing the sludge samples.