Application of advanced oxidation processes to doxycycline and norfloxacin removal from water

Abstract

Doxycycline (Dxy) and Norfloxacin (Nfx) have been oxidized by means of different technologies of increasing complexity. Preliminary experiments showed that activated carbon adsorption (1.0 g L⁻¹) of these antibiotics (C_Antibiotic = 5 × 10⁻⁵ M) led to a 60 and 85 % of total organic carbon (TOC) removal, however, a significant decrease in adsorption capacity was experienced after several reuses of the adsorbent. UV-C irradiation of Dxy (20 % removal in 2 h) or Nfx (90 % removal in 2 h) did not affect the initial TOC content of the solution while single ozonation (C_O3 gas inlet concentration = 15.0 ppm) led to the instantaneous disappearance of the parent compounds while TOC conversion values in the proximity of 40 % were obtained. Complex systems based on the combination of ozone, UV-C radiation, titanium dioxide and activated carbon led to similar TOC removals of the order of 70 and 65 % for Dxy and Nfx, respectively. An attempt has been made to calculate the quantum yield and direct ozonation rate constants for doxycycline and norfloxacin. Additionally, the best systems, i.e., the O₃ and O₃/UV-C processes, have been simulated by a pseudoempirical model by considering TOC as a surrogate parameter.

Keywords:

• Endocrine disruptor
• water remediation
• ozone
• kinetics
• mineralization
• norfloxacin
• doxycycline

Acknowledgments

The authors thank the economic support received from the CICYT of Spain and European FEDER Funds through projects CTQ 2009/13459/C05/05 and CSD2006-00044. Finally, Mr. Encinas acknowledges the Ministry of Science and Education of Spain through 6 grant FPI.