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Journal of Environmental Science and Health, Part A
Toxic/Hazardous Substances and Environmental Engineering
Volume 53, 2018 - Issue 12
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Original Articles

Preparation of carbon nanofibers/tubes using waste tyres pyrolysis oil and coal fly ash derived catalyst

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Pages 1115-1122 | Received 09 Mar 2018, Accepted 28 Apr 2018, Published online: 29 May 2018
 

ABSTRACT

In this study, two waste materials namely; coal fly ash (CFA) and waste tyres pyrolysis oil, were successfuly utilized in the synthesis of carbon nanofibers/tubes (CNF/Ts). In addition, Fe-rich CFA magnetic fraction (Mag-CFA) and ethylene gas were also used for comparison purposes. The carbons obtained from CFA were found to be anchored on the surface of the cenosphere and consisted of both CNTs and CNFs, whereas those obtained from Mag-CFA consisted of only multi-walled carbon nanotubes (MWCNTs). The study further showed that the type of carbon precursor and support material played an important role in determining the nanocarbon growth mechanism. The findings from this research have demonstrated that it is possible to utilize waste tyres pyrolysis oil vapor as a substitute for some expensive commercial carbonaceous gases.

Acknowledgments

The authors of this article would like to thank the South African Department of Science and Technology (DST) for the financial support towards HySA Infrastructure (Grant No. HTC004X), the Council for Scientific and Industrial Research (CSIR) for providing facilities and National Research Foundation (NRF) for funding the SA-Poland collaborative project (HTC071X). Any opinions, findings and/or recommendations expressed in this study are those of the authors and not of the funding bodies.

Additional information

Funding

South African Department of Science and Technology (DST) EIMH01X; Council for Scientific and Industrial Research (CSIR) EIMH01X; National Research Foundation (NRF) EIMH04X

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