Effect of ultrasonic homogenization on crude oil-water emulsion stability

Abstract

This research aims to evaluate the effect of ultrasonic processing parameters (power and sonication time), emulsion characteristics (water salinity and pH) and their interaction on oil-in-water emulsion stability for Cold Lake Blend (CLB) crude oil. Response surface methodology was used to design experimental runs, in which the parameters were investigated at five levels. Emulsion stability was evaluated by measuring creaming index, emulsion turbidity and microscopic image analysis. The effect of crude oil condition (fresh and weathered) on the emulsion stability was also investigated at the optimum sonication parameters and emulsion characteristics. The optimum condition was found at a power level of 76–80 W, sonication time of 16 mins, water salinity of 15 g/L NaCl, and pH of 8.3. Increasing sonication time beyond the optimum value had adverse effect on the emulsion stability. High water salinity (> 20 g/L NaCl) and pH (> 9) decreased the emulsion stability. These adverse effects intensified at higher power levels (> 80–87 W) and longer sonication times (> 16 mins). Interaction of parameters showed that the required energy to generate stable emulsion was within 60 − 70 kJ. Emulsion with fresh crude oil was more stable than those generated with the weathered oil.

Keywords:

• Crude oil in water
• emulsion
• stability
• ultrasonic
• creaming index
• turbidity difference

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

This research was supported by the Natural Sciences and Engineering Research Council of Canada (NSERC), and Fisheries and Oceans Canada’s Multi-Partner Oil Spill Research Initiative (MPRI).