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Natural Product Research
Formerly Natural Product Letters
Volume 19, 2005 - Issue 7
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Original Articles

Briarenol A, a new diterpenoid from a gorgonian 'Briareum sp. (Briareidae)

Ping-Jyun Sung National Museum of Marine Biology and Aquarium, 2 Houwan Road, Checheng, Pingtung 944, Taiwan, R.O.C.Correspondence[email protected]
,
Wan-Ping Hu Faculty of Biotechnology, Kaohsiung Medical University, Kaohsiung 807, Taiwan, R.O.C.
,
Lee-Shing Fang National Museum of Marine Biology and Aquarium, 2 Houwan Road, Checheng, Pingtung 944, Taiwan, R.O.C.
,
Tung-Yung Fan National Museum of Marine Biology and Aquarium, 2 Houwan Road, Checheng, Pingtung 944, Taiwan, R.O.C.
&
Jeh-Jeng Wang Faculty of Biotechnology, Kaohsiung Medical University, Kaohsiung 807, Taiwan, R.O.C.
Pages 689-694 | Received 01 Apr 2004, Published online: 20 Aug 2006
 
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Abstract

A new polyoxygenated briarane-type diterpenoid, briarenol A (1), has been isolated from a gorgonian coral belonging to the genus Briareum. The structure, including the relative stereochemistry of briarane 1, was elucidated by the interpretation of spectral data. The configuration of 1 was further supported by molecular mechanics calculations.

Acknowledgements

This research work was supported by the grants from the National Museum of Marine Biology and Aquarium and the National Science Council of the Republic of China (Contract no. NSC 92-2323-B-291-001) awarded to P.-J. Sung.

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