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Natural Product Research
Formerly Natural Product Letters
Volume 27, 2013 - Issue 20
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Research Article

Tricycloalternarene derivatives from endophytic fungus Alternaria tenuissima SY-P-07

Dong-Mei LiSchool of Traditional Chinese Materiel Medica, Shenyang Pharmaceutical University, Shenyang, 110016, People's Republic of China;Key Laboratory of Structure-Based Drug Design and Discovery, Ministry of Education, Shenyang Pharmaceutical University, Shenyang, 110016, People's Republic of China
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Yu-Hong ZhangSchool of Traditional Chinese Materiel Medica, Shenyang Pharmaceutical University, Shenyang, 110016, People's Republic of China;Key Laboratory of Structure-Based Drug Design and Discovery, Ministry of Education, Shenyang Pharmaceutical University, Shenyang, 110016, People's Republic of China
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Hai-Xia JiSchool of Traditional Chinese Materiel Medica, Shenyang Pharmaceutical University, Shenyang, 110016, People's Republic of China;Key Laboratory of Structure-Based Drug Design and Discovery, Ministry of Education, Shenyang Pharmaceutical University, Shenyang, 110016, People's Republic of China
,
Xin WuSchool of Life Science and Biopharmaceutics, Shenyang Pharmaceutical University, Shenyang, 110016, People's Republic of China
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Yue-Hu PeiSchool of Traditional Chinese Materiel Medica, Shenyang Pharmaceutical University, Shenyang, 110016, People's Republic of China;Key Laboratory of Structure-Based Drug Design and Discovery, Ministry of Education, Shenyang Pharmaceutical University, Shenyang, 110016, People's Republic of China
&
Jiao BaiSchool of Traditional Chinese Materiel Medica, Shenyang Pharmaceutical University, Shenyang, 110016, People's Republic of China;Key Laboratory of Structure-Based Drug Design and Discovery, Ministry of Education, Shenyang Pharmaceutical University, Shenyang, 110016, People's Republic of ChinaCorrespondence[email protected]
Pages 1877-1881 | Received 29 Oct 2012, Accepted 06 Jan 2013, Published online: 04 Mar 2013
 
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Abstract

A new tricycloalternarene, TCA 11a (1), was isolated from the culture broth of an endophytic fungus, Alternaria tenuissima SY-P-07, along with four known structurally related compounds 2–5. The structure of compound 1 was elucidated by extensive spectroscopic methods, especially 2D NMR, and the absolute stereochemistry of 1 was suggested on the basis of the CD spectral analysis and NOESY data.

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