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Natural Product Research
Formerly Natural Product Letters
Volume 32, 2018 - Issue 21
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Research Articles

A novel sesquiterpene derivative with a seven-membered B ring from Illigera aromatica

Jian-Wei DongCollege of Chemistry and Environmental Science, Qujing Normal University, Qujing, P.R. China;Functional Molecules Analysis and Biotransformation Key Laboratory of Universities in Yunnan Province, School of Chemical Science and Technology, Yunnan University, Kunming, P.R. China
,
Le CaiFunctional Molecules Analysis and Biotransformation Key Laboratory of Universities in Yunnan Province, School of Chemical Science and Technology, Yunnan University, Kunming, P.R. ChinaCorrespondence[email protected]
,
Xue-Jiao LiFunctional Molecules Analysis and Biotransformation Key Laboratory of Universities in Yunnan Province, School of Chemical Science and Technology, Yunnan University, Kunming, P.R. China
,
Yan ShuFunctional Molecules Analysis and Biotransformation Key Laboratory of Universities in Yunnan Province, School of Chemical Science and Technology, Yunnan University, Kunming, P.R. China
,
Jia-Peng WangFunctional Molecules Analysis and Biotransformation Key Laboratory of Universities in Yunnan Province, School of Chemical Science and Technology, Yunnan University, Kunming, P.R. China
&
Zhong-Tao DingFunctional Molecules Analysis and Biotransformation Key Laboratory of Universities in Yunnan Province, School of Chemical Science and Technology, Yunnan University, Kunming, P.R. ChinaCorrespondence[email protected]
Pages 2589-2595 | Received 29 Nov 2017, Accepted 09 Jan 2018, Published online: 25 Jan 2018
 
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Abstract

A novel sesquiterpene derivative with a seven-membered B ring, illigerine (1), along with four known compounds, 1-epi-chiliophyllin (2), 3,4-dihydroxyphenethyl alcohol (3), coniferyl alcohol (4) and phenylpropionic acid (5), were isolated from Illigera aromatica S. Z. Huang et S. L. Mo. Their structures were identified by 1D/2D NMR, HRESIMS and electronic circular dichroism spectra and the cytotoxic activity and inhibitory effect of NO production in LPS-stimulated RAW264.7 were also evaluated. This is the first report of sesquiterpene isolated from the genus Illigera.

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