Thermal characterisation of dye-intercalated K-10 montmorillonite ceramics using photoacoustic technique

Abstract

Thermal diffusivity (TD) measurements were performed on some industrially important dyes – auramine O (AO), malachite green and methylene blue (MB) – adsorbed K-10 montmorillonites using photoacoustic method. The TD value for the dye-adsorbed clay mineral was observed to change with a variation in dye concentration. The contribution of the dye towards TD was also determined. The repeatedly adsorbed samples with MB and AO exhibited a lower TD than the single-adsorbed samples. TD values of sintered MB samples were also obtained experimentally. These sintered samples exhibit a higher TD, although they show a trend similar to that of non-sintered pellets. A variation in dye concentration and sintering temperature can be used for tuning the TD value of the clay mineral to the desired level.

Keywords:

• photoacoustic technique
• thermal diffusivity
• montmorillonite
• dye intercalation

Acknowledgement

LKJ is thankful to University Grants Commission (UGC, Govt. of India) for financial assistance.