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Abstract
The frequency distribution of habit plane variant (HPV) clusters and the deviation from twin orientation relationships (ORs) at the junction plane (JP) are investigated by transmission electron microscopy together with theoretical evaluation of the kinematic compatibility (KC) at the JP in a β-titanium shape memory alloy. Even though there are more than 10 types of possible HPV clusters, only three types are formed. V-shaped couplings of HPVs by {111} type I twins (VI: 49%) and by ⟨211⟩ type II twins (VII: 42%) are the predominant types. A triangular morphology due to coupling of {111} type I twins is observed with a frequency of only 9%. These preferred morphologies are well explained by the degree of incompatibility (the rotation necessary for compatible connection of HPVs). The exact twin OR and KC are maintained at the JP in a VI cluster instead of KC at the habit plane (HP), whereas the JP in a VII cluster is incompatible and the ⟨211⟩ type II twin OR shows slight deviation at the JP by about 0.4°. The competition between KC at the JP and KC at the HP (invariant plane) is responsible for the frequency distribution of HPV clusters and the character of the interfaces in the self-accommodation microstructure.
Acknowledgements
This work was supported by the Global COE program of the Ministry of Education, Culture, Sports, Science and Technology, Japan. This work was also partially supported by the Advanced Low Carbon Technology Research and Development Program (JY230218 and JY240218) of the Japan Science and Technology Agency, the Funding Program for Next Generation World-Leading Researchers (LR015) and Grant-in-Aid for Fundamental Scientific Research (Wakate A, 24686077) from the Japan Society for the Promotion of Science.