Physical properties of cage-like compound UB₁₂

Abstract

Boron and uranium form three metallic borides having the chemical formulae UB₂, UB₄ and UB₁₂. In this study, we present the temperature variations of magnetic susceptibility, specific heat, electrical resistivity (performed in magnetic fields of 0 and up to 9 T), thermoelectric power and thermal conductivity measured on the bulk sample of UB₁₂. This dodecaboride behaves as a typical metal, being a Pauli paramagnet and exhibiting a large variety of physical properties due to its specific close-packed structure containing B₁₂ groups. We describe also an uncommon phenomenon observed in UB₁₂, that is, a fairly large scattering of the experimental resistivity data under application of a magnetic field at low temperatures and its systematic vanishing during heating of the sample. This effect is probably caused by inharmonious movement (rattling) of the uranium atoms inside the oversized coordination cage, B₂₄, reflected by applying the magnetic field. The specific heat, resistivity, thermoelectric power and heat transport data have been analysed in the framework of the low-frequency Einstein modes, which are mainly responsible for the phonon spectra behaviour in the system studied here.

Keywords:

• electrical transport
• magnetoresistance
• thermoelectric power

Acknowledgements

The authors are grateful to A. Solovjov for conducting additional (checking) electrical resistivity measurements in high magnetic fields on our sample of UB₁₂ performed in the Intern. High Field Laboratory of Wrocław. We are also express our thanks to H. Misiorek for carrying out the thermal conductivity measurements and to M. Samsel-Czekała for useful discussion and reading the manuscript.

Disclosure statement

No potential conflict of interest was reported by the authors.