Edge and surface antiferromagnetism in ABO₃ perovskite-type nanoparticle within the effective field theory

ABSTRACT

The edge and surface antiferromagnetic properties of the ABO₃ perovskite-type nanoparticle and their components (A, B and O) are investigated through the Effective Field Theory developed by Kaneyoshi. It is found that the Edge AntiFerroMagnetism (EAFM) causes a decrease in the Curie temperature and separation in the magnetizations. However, the Surface AntiFerroMagnetism (SAFM) causes a compensation behaviour (T_Comp = 1.23) in the total magnetisation of the ABO₃ perovskite-type nanoparticle. The magnetisation of the central B component has been affected by the edge antiferromagnetism more strongly than by the surface antiferromagnetism. Moreover, coercivity (Hc) and remanence magnetizations (Mr) decrease for the EAFM, but they increase for the SAFM. Triple hysteresis behaviour is obtained for the SAFM. Therefore, it is suggested that there is a strong relationship between the compensation behaviour and the triple hysteresis behaviour.

GRAPHICAL ABSTRACT

KEYWORDS:

• ABO₃-type magnetic perovskites
• antiferromagnetism
• compensation
• triple hysteresis
• effective field theory

Acknowledgements

We also thank David Robbins, Ph.D., Michael Lipscomb and Fitnat Tavacı for their proofreading.

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

This work was supported by Grant No FEFMAP/2018-0003 from Adiyaman University of Research Project Coordination (ADYUBAP), Turkey.