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Nucleosides, Nucleotides & Nucleic Acids Volume 25, 2006 - Issue 8
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Original Articles

Investigation of 1,3-Dipolar Cycloaddition Reactions of Unsaturated Nitrones in Ionic Liquids

M. Hornyák Department of Medicinal Chemistry, University of Szeged, Szeged, Hungary
,
Z. Kele Department of Medicinal Chemistry, University of Szeged, Szeged, Hungary
,
L. Kovács Department of Medicinal Chemistry, University of Szeged, Szeged, Hungary
,
P. Forgó Department of Organic Chemistry, University of Szeged, Szeged, Hungary
&
N. M. Howarth Department of Chemistry, Heriot-Watt University, Edinburgh, Riccarton, U.K.
Pages 867-870 | Received 15 Oct 2004, Accepted 17 Apr 2006, Published online: 16 Feb 2007
 
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Abstract

The effect of the media (achiral and chiral ionic liquids) on the stereochemistry of intramolecular 1,3-dipolar cycloaddition reactions of D-galactose-derived ω-unsaturated nitrones, leading to bicyclic isoxazolidines, has been investigated.

Presented at the XVI International Roundtable Conference, September 12–16, 2004.The financial support of the Wellcome Trust (grant no. 063879/Z/01/Z) and EU FP6 grant (TRIoH LSHB-CT-2003-503480) is gratefully acknowledged

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