Kinetics of Potassium Release from Calcareous Soils Under Different Land Use

Abstract

The rate of potassium (K) release from soils can significantly influence K fertility of soils. The aim of this study was to assess the impact of different land uses on K release from calcareous soils, within agricultural areas of western Iran. The kinetics of K release in 0.01 M CaCl₂ was studied in surface samples of 62 calcareous soils planted to pasture, orchard, garlic, leafy vegetables, wheat, and potato. Trend in K release kinetics was similar between land use types. We found that samples collected from pasture gave the lowest K release (245.2 mg kg⁻¹), whereas the highest values were measured on samples from leafy vegetables (449.6 mg kg⁻¹). Different models were used to describe K release. In general, Elovich, parabolic diffusion and power equation were found to be appropriate for modeling K release. The K release rate for the soils was estimated by parabolic equation and it was significantly different between land use types. The release rate was lower for pasture and wheat (averaged 16.1 and 25.1 mg kg⁻¹ min^−1/2, respectively) than leafy vegetables (27.4 mg kg⁻¹ min^−1/2) and potato (27.0 mg kg⁻¹ min^−1/2). When the rate of K released found from parabolic model regressed on K forms and soil properties, NH₄OAc-K, CaCl₂-K, pH, and EC appeared to be the most important K forms and soil properties influencing K release rates in these calcareous soils. The different K release and NH₄OAc-K or CaCl₂-K prior to K application both should be taken into account for potassium fertilizer application in different land uses.

Keywords:

• calcareous soil
• kinetic models
• land use
• potassium release

Notes

^a Sheep and poultry manures contains 13.6 and 40.3 g K kg⁻¹, respectively (Ranjbar and Jalali, 2012).

Values followed by the same letter within a column are not significantly different at probability of α = 0.05 level, according to Duncan test.

Values followed by the same letter within a column are not significantly different at probability of α = 0.05 level, according to Duncan test.

*^,**Significant at 5% and 1% level of significance, respectively.