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Fullerenes, Nanotubes and Carbon Nanostructures Volume 14, 2006 - Issue 2-3
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Original Articles

The Kinetics of Lipophilic Amine Addition to Fullerene C60

B. Ghanbari Petroleum Product Additive Research Department, Chemistry and Petrochemical Research Institute, Research Institute of Petroleum Industry (RIPI), Tehran, IranCorrespondence[email protected]
,
Z. Taheri Petroleum Product Additive Research Department, Chemistry and Petrochemical Research Institute, Research Institute of Petroleum Industry (RIPI), Tehran, Iran
,
M. Shekarriz Petroleum Product Additive Research Department, Chemistry and Petrochemical Research Institute, Research Institute of Petroleum Industry (RIPI), Tehran, Iran
,
S. Taghipoor Petroleum Product Additive Research Department, Chemistry and Petrochemical Research Institute, Research Institute of Petroleum Industry (RIPI), Tehran, Iran
,
B. Mohajerani Petroleum Product Additive Research Department, Chemistry and Petrochemical Research Institute, Research Institute of Petroleum Industry (RIPI), Tehran, Iran
&
M. Soleymani Jamarani Petroleum Product Additive Research Department, Chemistry and Petrochemical Research Institute, Research Institute of Petroleum Industry (RIPI), Tehran, Iran
Pages 315-319 | Published online: 22 Aug 2006
 
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Abstract

The reaction rate between hexadecylamine with fullerene is measured by a simple method for different temperatures and mole ratios of hexadecylamine to C60. Zero-order rate law can be assumed for the product formation in this reaction. The mole ratio of the amine:fullerene is optimized in terms of the conversion rate of C60. The reaction rate is slower than that expected for a simple collision between C60 and the amine. Temperature dependence of the reaction rate is determined and the activation energy is also estimated.

Acknowledgment

The work is fully supported by RIPI at National Iranian Oil Company.

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