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Molecular Crystals and Liquid Crystals Volume 440, 2005 - Issue 1
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Original Articles

Copper Atom Interaction with Mesogenic Cyanobiphenyls in Solid Co-Condensates

V. A. Timoshenko Lomonosov Moscow State University, Department of Chemistry, Moscow, Russia
,
A. A. Belyaev Lomonosov Moscow State University, Department of Chemistry, Moscow, Russia
,
Yu. N. Morosov Lomonosov Moscow State University, Department of Chemistry, Moscow, Russia
,
T. I. Shabatina Lomonosov Moscow State University, Department of Chemistry, Moscow, RussiaCorrespondence[email protected]
&
G. B. Sergeev Lomonosov Moscow State University, Department of Chemistry, Moscow, Russia
Pages 79-83 | Published online: 31 Aug 2006
 
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ABSTRACT

New metal-mesogenic systems based on copper and mesogenic cyanobiphenyls 5CB and 8CB have been produced by low temperature co-condensation of their component vapors. The formation of low temperature complexes of copper atoms with the cyanobiphenyl π-system in the solid state at 80–150 K was shown by ESR- and UV-Vis spectroscopic data. The thermal stability of the complexes and their thermal behavior on warming of the co-condensate samples up to room temperature are discussed.

Acknowledgments

The work was supported by RFBR grants 02-03-32469, 04-03-32748, Russian Federal Programme “Universities of Russia” and INTAS grant 2000-00911.

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