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Molecular Crystals and Liquid Crystals Volume 498, 2009 - Issue 1: Proceedings of the 11TH International Symposium on Advanced Display Materials and Devices (ADMD 2007) Part I
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Original Articles

Electrochemical Properties of Poly(α-methylbenzyl dipropargylamine) Prepared by the Cyclopolymerization of α-Methylbenzyl dipropargylamine

Tai-Long Gui Department of Electronic Science and Technology, Harbin Universityof Science and Technology, Harbin, China
,
Jia-Long Qiu Department of Electronic Science and Technology, Harbin Universityof Science and Technology, Harbin, China
,
Yue Wang Department of Electronic Science and Technology, Harbin Universityof Science and Technology, Harbin, China
,
Sang-Yeon Shim Department of Environ. & Applied Chem. Engineering, Kangnung National University, Gangneung, Korea
,
Sung-Ho Jin Department of Chemistry Education, Pusan National University, Pusan, Korea
,
Jong-Wook Park Department of Chemistry and Center for Nanotech. Res., The Catholic University, Bucheon, Korea
,
Kwon Taek Lim Division of Image and Information Engineering, Pukyong National University, Busan, Korea
&
Yeong-Soon Gal Polymer Chemistry Laboratory, College of Engineering, Kyungil University, Kyungsan, KoreaCorrespondence[email protected]
 show all
Pages 175-182 | Published online: 22 Jul 2010
 
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Abstract

The electrochemical properties of poly(α-methylbenzyl dipropargylamine) was studied by cyclic voltametry. Poly(α-methylbenzyl dipropargylamine) was prepared by the cyclopolymerization of α-methylbenzyl dipropargylamine in high yield. The photoluminescence peaks of the present polymer was observed at 443 nm corresponding to the photon energy of 2.80 eV. The cyclovoltamograms of the polymer exhibited the irreversible electrochemical behaviors between the doping and undoping peaks. It was found that the kinetics of the redox process of poly(MBDPA) might be mainly controlled by the electron transfer process from the experiment of the oxidation current density of poly(MBDPA) versus the scan rate.

Acknowledgments

This work was supported by the Korea Science and Engineering Foundation (KOSEF) grant funded by the Korean government (MEST) (No. R0l-2008-000-21056-0) and the Regional Innovation Center for Automotive Component Test (ACT-RIC of Kyungil University) from Regional Innovation Center Program of the Ministry of Knowledge Economy (MKE). The authors thank Mrs S. E. Chae of Korea Basic Science Institute-Taegu Branch for the measurement of 500-MHz FT-NMR spectra of polymers.

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