Abstract
The series of eight symmetric trimers, 4,4′-bis[ω-[2-methylbutyl-4′-(4″-phenyl)benzoateoxy]-3-bromo-4-alkyloxybenzylidene]-1,4-phenylenediamines has been synthesized and characterized. Except pentyl and undecyl homologues, the seven-ring chiral trimers exhibit the enantiotropic N* phase. In addition to the N* phase, the odd trimers with heptyl and nonyl spacers also exhibit the blue phase with platelet texture. The nematogenic properties of the trimers are attributed to the presence of two lateral bulky bromine atoms in the central mesogenic core. The suppression of mesophase thermal stability is largely due to the increase in molecular breadth at positions the bromine atoms are attached, which results in weaker overall lateral intermolecular attraction. The thermal properties of the trimers are also compared to those of the earlier reported analogous trimers that do not possess any lateral substituents in the mesogenic cores.
ACKNOWLEDGMENTS
The main author (G.-Y. Yeap) thanks the Ministry of Science, Technology, and Innovation (MOSTI) for the financial support through research grant no. 03-01-05-SF0366 (305/PKIMIA/613328). The authors also acknowledge Professor Ewa Gorecka (Warsaw University, Poland) and Professor Corrie T. Imrie (University of Aberdeen, Scotland) for suggestions and comments.
Notes
a The N*-BP and BP-I respective transition temperatures and enthalpies are unresolved in the DSC thermograms.
b The ΔSN*I/R values for 4c and 4e are obtained from the unresolved N*-BP and BP-I transitional entropies.