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Molecular Crystals and Liquid Crystals Volume 600, 2014 - Issue 1: KJF International Conference on Organic Materials for Electronics and Photonics (KJF 2013)
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Original Articles

Fluorescence Quench of Arylmaleimide with a Substituted Anthracene

Xiaochuan LiSchool of Chemistry and Chemical Engineering, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University, ChinaCorrespondence[email protected] [email protected]
,
Nan ZhaoSchool of Chemistry and Chemical Engineering, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University, China
,
Lihua YuSchool of Chemistry and Chemical Engineering, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University, China
&
Young-A SonBK21, Department of Advanced Organic Materials Engineering, Chungnam National University, South KoreaCorrespondence[email protected] [email protected]
Pages 14-21 | Published online: 17 Nov 2014
 
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Abstract

In this contribution, a bindolylmaleimide dye (ABM) with anthracene substituted through a covalent single bond was synthesized and characterized by NMR and mass spectroscopic techniques. Emission of ABM was investigated in various solvents. The emission intensity of ABM is weak in dioxane and toluene, and negligible in other solvents. Frontier molecular orbitals calculation for ABM was carried out based on Dmol3 package suit. Intramolecular charger transfer and free rotation of anthracene contributed to the non-radiative relaxation.

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