Synthesis and Characterization of a Series of Cholesterol-Based Liquid Crystalline Dimers with a Chiral (-)- Menthyl Terminal Group

Abstract

A novel series of cholesterol-based liquid crystalline (LC) dimers with a menthyl terminal group in the biphenyl base side have been synthesized. The chemical structures and LC properties of this series of compounds are characterized by FT-IR, ¹H-NMR, elemental analysis, hot-stage coupled polarizing microscopy and differential scanning calorimetry. All the dimers exhibit enantiotropic mesophases. These dimesogenic compounds with a short spacer are chiral nematic LCs, while with long spacers, they are SmA and chiral nematic LCs. Some of these LC dimers exhibit iridescent colors in their chial nematic (N*) states.

Keywords:

• Chiral nematic phase
• cholesterol
• dimesogenic
• liquid crystalline dimer
• menthyl