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Molecular Crystals and Liquid Crystals Volume 614, 2015 - Issue 1: 7th Italian-Japanese Workshop on Liquid Crystals and 10th National Meeting of the Italian Liquid Crystal Society
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Original Articles

Conformational and Orientational Determination from Dipolar Couplings in a Weakly Ordering Organic-Based Lyotropic and a Strongly Ordering Thermotropic Liquid Crystal

Maria Enrica Di PietroDipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, Arcavacata di Rende (CS), Italy;Equipe de RMN en milieu orienté, ICMMO, Université Paris-Sud, Orsay, FranceCorrespondence[email protected]
,
Giuseppina De LucaDipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, Arcavacata di Rende (CS), Italy
,
Giorgio CelebreDipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, Arcavacata di Rende (CS), Italy
,
Denis MerletEquipe de RMN en milieu orienté, ICMMO, Université Paris-Sud, Orsay, France
&
Christie AroulandaEquipe de RMN en milieu orienté, ICMMO, Université Paris-Sud, Orsay, France
Pages 39-53 | Published online: 18 Aug 2015
 
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Abstract

A weakly ordering organic-based lyotropic phase and a strongly ordering nematic liquid crystal have been used as NMR media for a parallel study of the conformation and orientational order of the same solute, trans-stilbene. A careful comparison allows to figure out some interesting conclusions on accessibility and precision of the experimental data and reliability and accuracy of the conformational descriptions into these two kinds of mesophases.

Funding

The present work has been supported by the “L’Oréal Italia per le Donne e la Scienza” program through the fellowship of M. E. Di Pietro. Moreover, G. Celebre, G. De Luca and M. E. Di Pietro thank University of Calabria and MIUR PRIN 2009 for financial support.

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