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Molecular Crystals and Liquid Crystals Volume 644, 2017 - Issue 1: Proceedings of the 19th International Symposium on Advanced Display Materials and Devices (ADMD 2015)
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Original Articles

Naphthalimide-coumarin: Dependent energy transfer cassette and its response to F−

Xiaochuan LiCollaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University, Xinxiang, Henan, P. R. China;Henan Key Laboratory of Green Chemical Media and Reactions, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan, P. R. ChinaCorrespondence[email protected] [email protected]
,
Saisai ShunCollaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University, Xinxiang, Henan, P. R. China
,
Dandan ShanCollaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University, Xinxiang, Henan, P. R. China
&
Young-A SonBK21, Department of Advanced Organic Materials Engineering, Chungnam National University, South KoreaCorrespondence[email protected] [email protected]
Pages 257-266 | Published online: 27 Apr 2017
 
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ABSTRACT

Naphthalimide and coumarin were bonded together with –NHN= being as the linkage. The emission behavior was investigated in various solvents. The energy transfer is independent in weak and medium polarity solvents. Efficient energy transfer occurred with the emission of it in polar solvent. In addition, it is highly emissive in polycarbonate and the energy transfer from coumarin to naphthalimide is more efficient. Another significant feature is its selective F− response. Upon the F− addition, the absorption around 444 nm shifted to 486 nm. And the new absorption band decreased and another new absorption band appeared around 574 nm.

Funding

This work was supported by the National Natural Science Foundation of China (21272060), PCSIRT (Grant no. IRT1061), and the Program for Innovative Research Team in Science and Technology in University of Henan Province (15IRTSTHN003). This study was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning (Grant No. 2016901050).

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