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Molecular Crystals and Liquid Crystals Volume 673, 2018 - Issue 1: 6th International Conference on Nanotechnology and Nanomaterials (NANO-2018), Part 1
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Articles

Luminescent properties of new polymer metal complexes based β-diketones and REE

Irina SavchenkoTaras Shevchenko National University of Kyiv, 64/13, Volodymyrs’ka Str., Kyiv01601, Ukraine; Correspondence[email protected]
,
Oleksandra BerezhnytskaV.I. Vernadsky Institute of General and Inorganic Chemistry of the NASU, 32/34, Akad. Palladin Ave., Kyiv03142, Ukraine; ;National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37, Prosp. Peremohy, Kyiv03056, Ukraine;
,
Yaroslav FedorovV.I. Vernadsky Institute of General and Inorganic Chemistry of the NASU, 32/34, Akad. Palladin Ave., Kyiv03142, Ukraine;
,
Sergiy SmolaA.V. Bogatsky Physico-Chemical Institute of the NASU, 86, Lustdorf Road, Odesa65000, Ukraine
&
Olena TrunovaV.I. Vernadsky Institute of General and Inorganic Chemistry of the NASU, 32/34, Akad. Palladin Ave., Kyiv03142, Ukraine;
Pages 48-60 | Published online: 19 Jun 2019
 
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Abstract

The Sm(III) complexes with 2-methyl-5-phenylpenten-1-3,5-dione and their phenanthroline adduct were synthesized. The polycomplexes on their basis and copolymers with styrene and methylmethacrylate at different ratios of monomers were obtained by free-radical polymerization. The results of above studies have shown that the configuration of the chelate unit is unchanged during the polymerization. As a result, the type of coordination was determined and the structure of coordination polyhedra was assumed. The luminescence spectra of obtained metallocomplexes and polymers in solutions and solid state are investigated and analyzed.

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