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LOW-DIMENSIONAL SOLIDS AND MOLECULAR CRYSTALS

Syntheses, structures and luminescent properties of Sm(III) and Dy(III) coordination polymers with two organic dicarboxylates

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Pages 113-121 | Published online: 18 Oct 2021
 

Abstract

Two coordination polymers [Sm2(3,5-pdc)(1,2-bdc)2(H2O)4]n (1) and {[Dy2(3,5-pdc)(1,2-bdc)2(H2O)4]·2H2O}n (2) were synthesized by hydrothermal method. The crystal structures were tested by X-ray single crystal diffraction. 1 was 3D porous network structure while 2 was 2D layered structure. They both emitted the characteristic fluorescence of Sm(III) or Dy(III) with ultraviolet light excitations. The lifetimes of excited states for Sm(III) and Dy(III) were measured.

Conflicts of interest

There are no conflicts to declare.

Additional information

Funding

We gratefully acknowledge financial support from Xuchang University.

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