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LIQUID CRYSTALS

Image sticking and long-term stability of polymer-sustained-alignment liquid crystal cell produced from the mixed monomers containing phenanthrene- and benzophenon-moieties

, &
Pages 10-21 | Published online: 23 May 2022
 

Abstract

As a model of polymer-sustained-alignment liquid crystal display (PSA-LCD), the LC cells having the PSA layers (PSA-LC cells) formed by mixed monomers of 2,7-dimethacryloyl-oxy-phenanthrene (2,7-DMAPhen) and 4,4’-dimethacryloyl-oxy-benzophenon (4,4’-DMABenz) were fabricated, and image sticking parameters and long-term stability under LED-backlight exposure were investigated. Residual direct current voltage (VrDC) and difference in pretilt angle (Δtilt) before and after application of alternate current voltage were evaluated as the image sticking parameters. The VrDC was improved with the addition of a small amount of 4,4’-DMABenz because the concentrations of radical and/or ion in the LC layer had decreased significantly. It was shown that with the addition of 3.8 wt% of 4,4’-DMABenz in the mixed monomers, VrDC can be kept low without increasing Δtilt. Voltage holding ratio was maintained high under the LED-backlight exposure for 1,000 h, indicating that the PSA-LC cell shows high long-term stability. Hence we expect that the proposed PSA-LC cell would be useful for high luminance LCDs.

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