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Molecular Crystals and Liquid Crystals Volume 768, 2024 - Issue 1
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Research Article

Side-chain azoquinoline polymers: synthesis and photochemical properties

Vitaliy Smokala Department of Chemistry of Macromolecular Compounds Taras Shevchenko National University of Kyiv, Kyiv, UkraineCorrespondence[email protected]
ORCID Iconhttps://orcid.org/0000-0001-6832-8625View further author information
ORCID Icon,
Dmytro Khomenkob Department of Inorganic Chemistry, Taras Shevchenko National University of Kyiv, Kyiv, Ukraine;c Enamine Ltd. (www.enamine.net), Kyiv, UkraineView further author information
,
Roman Doroshchukb Department of Inorganic Chemistry, Taras Shevchenko National University of Kyiv, Kyiv, Ukraine;c Enamine Ltd. (www.enamine.net), Kyiv, UkraineView further author information
,
Rostyslav Lampekab Department of Inorganic Chemistry, Taras Shevchenko National University of Kyiv, Kyiv, UkraineView further author information
&
Anna Panovad V. Bakul Institute for Superhard Materials of the National Academy of Sciences of Ukraine, Kyiv, UkraineView further author information
Pages 89-97 | Published online: 18 Jul 2023
 
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Abstract

The new methacrylic azo containing monomers with side chain quinoline moiety were synthesized by reaction alcohols with methacryloyl chloride, the polymers based on new monomers were synthesized by free radical polymerization. Polymers were characterized by 1HNMR spectroscopy. The results of photochemical and optical activities of the corresponding polymers are presented.

Additional information

Funding

This work was partially supported by National Research Foundation of Ukraine. Project 2020.02/0022. Plasmon hybrid nanosystems "metal-polymer-fluorophore" with enhanced optical response for photonics and biomedical applications and the Ministry of Education and Science of Ukraine: Grant of the Ministry of Education and Science of Ukraine for perspective development of a scientific direction “Mathematical sciences and natural sciences” and was carried out in the framework of project “Hybrid nanosystems on smart polymers for biotechnology and medicine” (no. 0122U001818).

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