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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 36, 2006 - Issue 2: Part II: Nanoscience and Nanotechnology Papers selected from the International Conference on Nanomaterials (NANAO 2005)
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Original Articles

Optical and Magnetic Properties of Mn‐Incorporated ZnS Nanorods

Soumitra Kar Department of Materials Science, Indian Association for the Cultivation of Science, Kolkata, India
,
Subhajit Biswas Department of Materials Science, Indian Association for the Cultivation of Science, Kolkata, India
&
Subhadra Chaudhuri Department of Materials Science, Indian Association for the Cultivation of Science, Kolkata, IndiaCorrespondence[email protected]
Pages 193-196 | Received 20 Jul 2005, Accepted 28 Nov 2005, Published online: 19 Aug 2006
 
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Abstract

Mn‐doped ZnS (MnxZn1‐xS) nanorods were synthesized by a simple solvothermal process. Synthesized nanorods were single crystalline. Mn incorporation in the ZnS lattice induces a phase transformation from hexagonal wurtzite to cubic zincblende structure. Intense orange luminescence at ∼585 nm was observed for the doped ZnS nanorods. Six‐hyperfine splitting was observed in the EPR spectra for lower Mn concentrations and broad Lorentzian‐shaped EPR spectra were obtained for higher Mn concentrations.

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