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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 37, 2007 - Issue 1
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Original Articles

Copper Conjugates of Knoevenagel Condensates of Curcumin and their Schiff Base Derivatives: Synthesis, Spectroscopy, Magnetism, ESR, and Electrochemistry

Ajit P. Zambre Drug Design and Molecular Medicine Group, Department of Chemistry, University of Pune, Pune, India; Department of Medicinal Chemistry, Bharati Vidyapeeth University Poona College of Pharmacy, Pune, India
,
Abeda Jamadar Department of Medicinal Chemistry, Bharati Vidyapeeth University Poona College of Pharmacy, Pune, India
,
Subhash Padhye Drug Design and Molecular Medicine Group, Department of Chemistry, University of Pune, Pune, IndiaCorrespondence[email protected]
&
V. M. Kulkarni Department of Medicinal Chemistry, Bharati Vidyapeeth University Poona College of Pharmacy, Pune, India
Pages 19-27 | Received 29 Sep 2006, Accepted 14 Nov 2006, Published online: 30 Mar 2007
 
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Novel copper(II) complexes of curcumin Knoevenagel condensates and their Schiff bases have been synthesized and characterized. All copper complexes possess distorted square‐planar geometries with 1:1 metal to ligand stoichiometry capable of stabilizing Cu2+/Cu1+ redox couples in the range 0.34 to 0.40 V. ESR spectral features are consistent with g‖>g⊥>2.0 suggesting monomeric nature of copper complexes having dx 2 −y 2 ground state.

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