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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 37, 2007 - Issue 7
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Original Articles

Selective Oxidation of Benzoins to Benzils with Ferric (III) Nitrate Supported on Graphite Reagent

Ji‐Dong Lou College of Life Sciences, China Institute of Metrology, Hangzhou, Zhejiang, ChinaCorrespondence[email protected]
,
Mei‐Hua Piao College of Life Sciences, China Institute of Metrology, Hangzhou, Zhejiang, China
,
Feng Li Instituto de Tecnologia Química e Biológica, Universidade Nova de Lisboa, Oeiras, Portugal
,
Li Li Instituto de Tecnologia Química e Biológica, Universidade Nova de Lisboa, Oeiras, Portugal
&
Chun‐Ling Gao Center for Prostate Disease Research, Uniformed Service University of Health Science, Bethesda, MD, USA
Pages 553-555 | Received 06 Feb 2007, Accepted 02 Apr 2007, Published online: 14 Sep 2007
 
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Selective oxidation of benzoins into corresponding benzils using ferric (III) nitrate nonahydrate supported on graphite reagent under heterogeneous conditions and reflux is described. The present oxidations are completed within 3 hours with the yield between 82–95%. It has the main advantage of being readily available, inexpensive, and relatively non‐toxic oxidation reagent.

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