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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 37, 2007 - Issue 10
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Original Articles

Early Transition Metal‐Catalyzed Polymerization in Aqueous Medium: A Short Account of Our Recent Endeavour

Manish Bhattacharjee Department of Chemistry, Indian Institute of Technology, Kharagpur, IndiaCorrespondence[email protected]
&
Braja N. Patra Department of Chemistry, Indian Institute of Technology, Kharagpur, India
Pages 749-755 | Received 13 Nov 2006, Accepted 23 May 2007, Published online: 29 Nov 2007
 
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Contrary to the general notion, metllocene dichlorides, Cp2MCl2 (M=Ti, Zr, or V) have been found to catalyze polymerization of olefins in aqueous medium to afford high molecular weight polymers with low molecular weight distribution.

Dedicated to Professor Herbert W. Roesky on the occasion of his 70th birthday.

We thank Department of Science & Technology, Government of India, New Delhi, for financial assistance.

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