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Abstract
One novel dimeric complex [Cu 2 (L) 2 (μ 2 -L) 2 (CH 3 OH) 6 ] has been prepared by the reaction of organic ligand 3-(4-carboxyphenylhydrazono) pentane-2,4-dione (HL) with copper(II) ion in solution. It is a binuclear complex, in which two Cu(II) ions are bridged by two carboxyates from two L−. It was characterized by elemental analysis, IR and single X-ray determinations. Also, reaction conditions, thermostability, and fluorescent properties of the complex were researched.
The authors gratefully acknowledge the financial support by the National Natural Science Foundation of China (20501017), the Key Project of Chinese Ministry of Education (207067), the Scientific Research Foundation for the Returned Overseas Chinese Scholars of Chinese Ministry of Education, the Foundation for University Key Young Teacher by the Henan Educational Committee, and the Natural Science Foundation of Henan Educational Committee (2007150040; 2009A150028).