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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 40, 2010 - Issue 10
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Original Articles

A Novel (3,6,6)-Connected 3D Supramolecular Framework Constructed from 2D (4,4) Coordination Network [Pb(H2pimdc)2(H2O)2]n

Ni Wang College of Mechanical & Material Engineering, Functional Materials Research Institute, China Three Gorges University, Yichang, P. R. China; Department of Chemistry & Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan′an University, Yan′an, P. R. China
,
Dong-Sheng Li College of Mechanical & Material Engineering, Functional Materials Research Institute, China Three Gorges University, Yichang, P. R. China; Department of Chemistry & Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan′an University, Yan′an, P. R. China
,
Jun Zhao College of Mechanical & Material Engineering, Functional Materials Research Institute, China Three Gorges University, Yichang, P. R. China
,
Peng Zhang College of Mechanical & Material Engineering, Functional Materials Research Institute, China Three Gorges University, Yichang, P. R. China
,
Qiu-Fen He College of Mechanical & Material Engineering, Functional Materials Research Institute, China Three Gorges University, Yichang, P. R. China
,
Xi-Jun Ke College of Mechanical & Material Engineering, Functional Materials Research Institute, China Three Gorges University, Yichang, P. R. China
&
Cai Li College of Mechanical & Material Engineering, Functional Materials Research Institute, China Three Gorges University, Yichang, P. R. China
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Pages 762-767 | Received 19 May 2010, Accepted 19 Jul 2010, Published online: 03 Dec 2010
 
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Abstract

A new PbII-compound, [Pb(H2pimdc)2(H2O)2]n (1)(H3pimdc = 2-propyl-4,5-imidazole dicarboxy- late), has been hydrothermally synthesized and characterized. Single crystal X-ray diffraction reveals that in 1, μ3-H2pimdc− anion act as linker to connect PbII into 2D (4,4) coordination network, which are further extended to a 3D supramolecular network with (3,6,6)-connected (32·42·52·64·74·10) (32·42·52·66·73)2(4·62)2 topology through R1 2(8) H-bonding rings. In additional, photoluminescence and thermal stability of 1 have been investigated as well.

Acknowledgments

This project was supported by the NSF of China (20773104, 21073106), NCET (NCET-06-0891), the NSF HB (2008CDB030), and the IPHPEO (Z20091301and Q20101203).

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