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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 41, 2011 - Issue 10
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Original Articles

Efficient Oxidative Cleavage of Oximes to Their Corresponding Carbonyl Compounds with Chromic Acid Supported on Kieselguhr Under Heterogeneous Conditions

Ji-Dong Lou College of Life Sciences, China Jiliang University, Hangzhou, Zhejiang, P. R. China; Sirnaomics, Inc., Gaithersburg, Maryland, USA
,
Xiu Lian Lu College of Life Sciences, China Jiliang University, Hangzhou, Zhejiang, P. R. China
,
Li-Hong Huang College of Life Sciences, China Jiliang University, Hangzhou, Zhejiang, P. R. China
,
Changhe Zhang Center for the Research and Technology of Agro-Environmental and Biological Sciences (CITAB)/Department of Biology and Environment, Universidade de Trás-os-Montes e Alto Douro (UTAD), Vila Real, Portugal
,
Qiang Wang Sirnaomics, Inc., Gaithersburg, Maryland, USA
&
Xiao-Nan Zou College of Life Sciences, China Jiliang University, Hangzhou, Zhejiang, P. R. China
Pages 1278-1281 | Received 17 Apr 2011, Accepted 30 May 2011, Published online: 02 Dec 2011
 
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Abstract

An efficient oxidative cleavage of oximes to their corresponding carbonyl compounds with chromic acid supported on kieselguhr reagent under heterogeneous conditions at reflux with a yield between 86 and 96% is described. In these reaction conditions, deoximation of aldoximes required a longer reaction time than that of ketoximes, and the conditions are not suitable for deoximation of aliphatic aldoximes.

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