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Original Articles

Synthesis, Characterization, and Structure of a Silver(I) Compound With Thymine

, , , , &
Pages 313-316 | Received 01 Jul 2011, Accepted 31 Jul 2011, Published online: 24 Apr 2012
 

Abstract

The interaction of [Ag(PPh3)2(CH3COO)] (1) with thymine led to the displacement of the acetate ligand forming the mononuclear compound [Ag(PPh3)2(C5H5N2O2)] (2). This compound has been characterized by IR, NMR, element analysis, and X-ray crystallographic analysis. Crystal structure of 2 shows each Ag ion is three-coordinated by two P atoms of the triphenylphosphino ligands and one N atoms of the thymine, which is stabilized by two intermolecular N-H…O and O-H…O hydrogen bonding interactions.

Acknowledgments

The authors are grateful to the Project of the National Ministry of Education (000049)and Ministry of Personnel(01017-080002), the State Key Laboratory of Chemical Resource Engineering (Beijing University of Chemical Technology) and Qianjiang Project of Zhejiang Province (01002-123-080050) for financial support.

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