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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 42, 2012 - Issue 4
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Original Articles

Synthesis, Structure, and Photoluminescent Property of a Novel 2D Silver(I) Polymer Based on Short Ag-Ag Interactions

Qiao-Juan Su Tianjin Key Laboratory on Technologies Enabling Development of Clinical Therapeutics and Diagnostics (Theranostics) School of Pharmacy, Tianjin Medical University, Tianjin, P. R. China; Department of Pharmacy, Armed Police Corps Hospital in Fujian, Fuzhou, P. R. China
,
Zhong-Ying Ma Tianjin Key Laboratory on Technologies Enabling Development of Clinical Therapeutics and Diagnostics (Theranostics) School of Pharmacy, Tianjin Medical University, Tianjin, P. R. China
,
Yan Ouyang Tianjin Key Laboratory on Technologies Enabling Development of Clinical Therapeutics and Diagnostics (Theranostics) School of Pharmacy, Tianjin Medical University, Tianjin, P. R. China
,
Yan-Wen Zhang Tianjin Key Laboratory on Technologies Enabling Development of Clinical Therapeutics and Diagnostics (Theranostics) School of Pharmacy, Tianjin Medical University, Tianjin, P. R. China
,
Cheng-Zhi Xie Tianjin Key Laboratory on Technologies Enabling Development of Clinical Therapeutics and Diagnostics (Theranostics) School of Pharmacy, Tianjin Medical University, Tianjin, P. R. China
&
Jing-Yuan Xu Tianjin Key Laboratory on Technologies Enabling Development of Clinical Therapeutics and Diagnostics (Theranostics) School of Pharmacy, Tianjin Medical University, Tianjin, P. R. China
Pages 493-497 | Received 05 Apr 2011, Accepted 07 Aug 2011, Published online: 01 May 2012
 
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Abstract

A new two-dimensional (2D) polymer, [Ag(2-Clnic)]n (2-Clnic = 2-chloronicotinate) (1), has been synthesized and characterized by IR, elemental analysis, single-crystal X-ray diffraction, and luminescence spectroscopy. X-ray crystal analysis reveals that complex 1 is constructed through π-π stacking and Ag…O interactions, which provide important roles in the assembly of intriguing structures and specific photophysical properties. In the solid state at room temperature, 1 is found to be luminescent with a purple emission band at 411 nm upon excitation at 360 nm.

Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 20971099) and the Science Foundation of Tianjin Medical University (No. 2010ky11).

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