Abstract
The Schiff base 2-ethoxysalicylaldehydethiosemicarbazone (HL) derived from 3-ethoxysalicylaldehyde and thiosemicarbazide, and its centrosymmetric trinuclear cadmium(II) complex [Cd3L4]·2NO3·2H2O, have been successfully prepared. The structure of the complex was characterized by elemental analyses, IR spectrum, and single-crystal X-ray crystallographic determination. The complex crystallizes in the monoclinic space group C2/c with unit cell dimensions a = 15.102(2) Å, b = 19.049(2) Å, c = 21.303(3) Å, β = 107.212(2)°, V = 5853.8(12)
3, Z = 4, R
1 = 0.0318, and wR
2 = 0.0765. The Schiff base coordinates to the Cd atoms through the phenolate O, ether O, imino N, and S atoms. The terminal Cd atoms of the complex are coordinated by six donor atoms from two Schiff base ligands. The central Cd atom of the complex is coordinated by eight O atoms from four Schiff base ligands. The effect of the Schiff base and the complex on the antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans was studied.
Acknowledgments
This research was supported by the National Science Foundation of China (nos. 20676057 and 20877036) and the Top-class Foundation of the Pingdingshan University (no. 2008010).