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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 44, 2014 - Issue 5
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Original Articles

Photophysical Properties of a Novel Metalloporphyrin FeBr [TCPP-(CH3)4]·0.5(CH3OH) (TCPP = meso-tetra (4-Carboxyphenyl) Porphyrin)

Wen-Tong Chen Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jinggangshan University, Ji’an, Jiangxi, P. R. China
Pages 702-705 | Received 01 Mar 2013, Accepted 05 Mar 2013, Published online: 16 Dec 2013
 
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Abstract

A new porphyrin FeBr [TCPP-(CH3)4]·0.5(CH3OH) (1), (TCPP = meso-tetra (4-carboxyphenyl) porphyrin), has been synthesized via a solvothermal reaction and characterized by X-ray diffraction. Compound 1 is characterized as an isolated structure with a distorted nonplanar porphyrin macrocycle and an embedded FeIII ion coordinating to four pyrrole nitrogen atoms and one bromine atom. The TCPP is esterified with methanol. The reaction mechanism and photophysical properties were explored.

Acknowledgments

This work was supported by the financial support of the National Science and Technology Support Program of the Ministry of Science and Technology of P. R. China (2012BAC11B01).

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