Advanced search
Publication Cover
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 44, 2014 - Issue 7
Submit an article Journal homepage
112
Views
11
CrossRef citations to date
0
Altmetric
Original Articles

Syntheses, Crystal Structures, and Magnetic Properties of Two Meta-Substituted Benzyl Triphenylphosphinium Tetra(isothiocyanate)cobaltate(II) Complexes

Wei-Qiang Chen Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
,
Li-Jie Su Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
,
Xiao-Qi Cai Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
,
Jing-Jing Yang Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
,
Ye-Long Qian Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
,
Xiao-Ping Liu Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
,
Le-Min Yang Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
,
Jia-Rong Zhou Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
&
Chun-Lin Ni Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
 show all
Pages 980-985 | Received 01 Mar 2013, Accepted 10 Apr 2013, Published online: 04 Mar 2014
 
Sample our Engineering & Technology journals, sign in here to start your access, latest two full volumes FREE to you for 14 days

Abstract

Two new complexes of tetra(isothiocyanate)cobalt(II) dianion and meta-substituted benzyl triphenylphosphinium, [3BrBzTPP]2[Co(NCS)4] (1) and [3CNBzTPP]2[Co(NCS)4] (2) ([3BrBzTPP]+ = 1-(3′-bromobenzyltriphenylphosphonium and [3CNBzTPP]+ = 1-(3′-cyanobenzyltriphenylphosphonium), were prepared and characterized by elemental analysis, FT–IR, UV-vis spectra, ESI-MS, and single-crystal X-ray diffraction method. Both 1 and 2 crystallize in monoclinic P2(1)/c, and the Co(II) ion of the [Co(NCS)4]2− anion shows a distorted tetrahedral coordination geometry. The C-H···S hydrogen bonds and p···π interaction found in 1 and 2 consolidate the stacking of the crystal. Magnetic susceptibility measurement in the temperature range 2–300 K shows that 1 and 2 exhibit a weak antiferromagnetic coupling behavior.

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 674.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.