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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 44, 2014 - Issue 7
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Original Articles

Synthesis, Crystal Structure, and Biological Activity of an Mn(II) Complex Derived from 2,6-diacetylpyridine bis(N4-methylthiosemicarbazone)

Y. Lu Henan Key Laboratory of Polyoxometalates, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, P. R. China
,
J. Li Basic Experiment Teaching Center, Henan University, Kaifeng, P. R. China
,
M. Li Henan Key Laboratory of Polyoxometalates, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, P. R. China
&
D. Chen Institute of Fine Chemistry and Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, P. R. China
Pages 1068-1072 | Received 19 Mar 2013, Accepted 10 Apr 2013, Published online: 04 Mar 2014
 
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Abstract

Transition metal complex [Mn(H2L)(H2O)2](CH3COO)2 (1), where H2L = 2,6-diacetylpyridine bis(N 4-methylthiosemicarba- zone), has been synthesized and characterized by elemental analysis, IR, mass spectrometry, and single-crystal X-ray diffraction. Complex 1 is depicted as a monomeric, seven-coordinated complex formed with one Mn(II) ion, one pentadentate N3S2 thiosemicarbazone ligand, and two oxygen atoms from two water molecules. Biological studies, carried out in vitro against K562 leukemia cells, have shown that the thiosemicarbazone moiety and its manganese(II) complex show distinctive differences in the biological property.

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